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dc.contributor.authorSilva, Ricardo Figueira da
dc.date.accessioned2023-12-22T03:03:09Z-
dc.date.available2023-12-22T03:03:09Z-
dc.date.issued2004-03-30
dc.identifier.citationSilva, Ricardo Figueira da. Investigação de ácidos fenólicos em amostras de mel por cromatografia líquida de alta eficiência e sua aplicação na caracterização da origem floral. 2004. 82 f. Dissertação (Programa de Pós-Graduação em Química) - Universidade Federal Rural do Rio de Janeiro, Seropédica-RJ .por
dc.identifier.urihttps://rima.ufrrj.br/jspui/handle/20.500.14407/14560-
dc.description.abstractEste trabalho descreve a investigação da presença de ácidos fenólicos em treze amostras de méis de eucalipto e seis amostras de méis silvestres obtidos de diferentes regiões geográficas. As amostras de méis foram analisadas por cromatografia líquida de alta eficiência com detector de UV-visível e fotodiodo. A análise do perfil cromatográfico associado ao estudo dos espectros de ultravioleta obtidos pelo detector de fotodiodo dos méis de eucalipto permitiu identificar os ácidos gálico, vanílico, para-cumárico, ferulico e cinâmico, enquanto para os méis silvestres foram identificados os ácidos gálico, vanílico, clorogênico, orto-cumárico, cinâmico e 2-metoxicinâmico. A técnica de cromatografia líquida de alta eficiência mostrou-se eficiente, reprodutiva e de fácil manipulação para análise dos ácidos fenólicos nas dezenove amostras de méis estudados. Dada a sua reprodutibilidade e versatilidade poderá vir a ser usada na identificação da origem floral e no controle analítico dos méis comercializados, auxiliando assim a análise palinológica. Os perfis cromatográficos dos ácidos fenólicos para os méis de uma mesma espécie floral, oriundo de diferentes regiões geográficas, não sofreram alterações qualitativas e quantitativas drásticas, sugerindo que os compostos fenólicos estudados podem servir como marcadores químicos para a caracterização botânica do mel e/ou geográfica. Os méis silvestres foram estudados em menor número, sendo necessário um estudo mais aprofundado para a confirmação inequívoca da composição química deste mel. Um quantidade maior de amostras de méis de mesma origem floral, porém de diferentes origens geográficas deverão ser analisadas para corroborar na utilização desses ácidos fenólicos como marcadores químicos na origem botânica e/ ou geográfica dos méis brasileiros. Palavras chaves: Ácidos fenólicos, Mel, Cromatografia líquida de alta eficiência, Origem botânica.por
dc.formatapplication/pdf*
dc.languageporpor
dc.publisherUniversidade Federal Rural do Rio de Janeiropor
dc.rightsAcesso Abertopor
dc.subjectÁcidos fenólicospor
dc.subjectMelpor
dc.subjectCromatografia líquida de alta eficiênciapor
dc.subjectOrigem botânicapor
dc.subjectPhenolic acidseng
dc.subjecthoneyeng
dc.subjectHPLCeng
dc.subjectbotanic origineng
dc.titleInvestigação de ácidos fenólicos em amostras de mel por cromatografia líquida de alta eficiência e sua aplicação na caracterização da origem floralpor
dc.title.alternativeInvestigation of phenolic acids in honey by highpressure liquid chromatography and its application for the caracterization of the botanic originpor
dc.typeDissertaçãopor
dc.description.abstractOtherThis work describes the investigation of phenolic acids in 13 samples of eucalyptus honey and 5 samples of wild honeys from different geographical regions. The samples were analyzed by high-pressure liquid chromatography with a diode array detector. The analysis of UV spectra obtained with the eucalyptus honeys showed the presence of gallic, vanillic, p-coumaric, ferulic and cinnamic acids while the wild honeys contain mainly gallic, vanillic, chlorogenic, o-coumaric, cinnamic and 2-methoxy cinnamic acids. The HPLC technique has been shown to be effective and reproducible. Given this high reproducibility and versatility, this technique may become useful in the identification of the floral origin in the control of commercial honeys, thus analytical helping the palinological analysis. The chromatographical profiles of the phenolic acids from honeys of the same species coming from different regions did not show any major qualitative or quantitative differences suggesting that these phenolic compounds may serve as chemical markers for the botanical or geographical chacterization of honeys. The number of wild honeys analyzed was small and a more through investigation must be carried out in order to uequivocally confirm their composition. A larger number of samples belongings to the same floral origin but coming from different regions showed be analyzed to corroborate their use chemical markers.eng
dc.contributor.advisor1Castro, Rosane Nora
dc.contributor.advisor1Latteshttp://lattes.cnpq.br/5479814788308057por
dc.contributor.referee1Castro, Rosane Nora de
dc.contributor.referee2Barreto, Alaíde de Sá
dc.contributor.referee3Carvalho, Mário Geraldo de
dc.contributor.referee4Oliveira, Márcia Cristina Campos de
dc.publisher.countryBrasilpor
dc.publisher.departmentInstituto de Ciências Exataspor
dc.publisher.initialsUFRRJpor
dc.publisher.programPrograma de Pós-Graduação em Químicapor
dc.relation.referencesADCOCK, D. 1962.The effect of catalase on the inhibine and peroxide values of various’ honeys. Journal of Apicultural Research; 1, 38-40. ALLEN, K. L., MOLAN, P. C. & REID, G. M. 1991. The variability of the antibacterial activity of honey. Apiacta, 26, 114-21. ALLEN, K. L., MOLAN, P. C. & REID, G. M. 1991a. A survey of the antibacterial activity of some New Zealand honeys. Journal of Pharmacy and Pharmacology, 43, 817-22. AMIOT, M. J.; AUBERT, S.; GONNET, M. & TACCHINI, M. 1989. The phenolic compounds in honeys: preliminary study upon identification and family quantification. Apidologie, 20(2), 115-125. AMIOT, M.J.; SABATIER, S.; TACCHINI, M. e AUBERT,S. 1992. Identification of Flavonoids in Sunflower Honey. J. Food Sci.; 57(3), 773-777. ANDRADE, P.; FERRERES, F. E AMARAL, M.T.1997. Analysis of Honey phenolic acids by HPLC, its application to honey botanical characterization. J.Liq. Chrom. & Rel. Technol., 20 (14), 2281-2288. ARMON, P.J. 1980. The use of honey in the treatment of infected wounds. Tropical Doctor, 10: 91. AUBERT, S. & GONNET, M. 1983. Mesure de Ia couleur des miels. Apidologie, 14 (2): 105-118 AURELI, P.; HATHEWAY, C.L.; FENICIA, L.; FERRINI, A.M. 1986. Prime segnalazaioni di casi di botulismo infantile in Italia. Ann. 1st. Super. Sanita', 22: 855- 858 AZEREDO, M.A.A. & AZEREDO, L.C. 1999. Características físico-químicas dos méis do município de São Fidélis-RJ. Ciência e Tecnologia de Alimento,19(1),3-7. AZOUBEL, M.L. 1986. Análise da Origem Floral de Méis do Nordeste. Resumos do VII Congresso Brasileiro de Apicultura, Salvador, Bahia: 27. BARTH, O.M. 1989. O Pólen no mel Brasileiro. Rio de Janeiro. Luxor. 150p. BARTH, M.O.1990. Pollen in monofloral honeys from Brazil. J.Apic. Research, 29(2):89-94. BARTH, O.M.1996. Monofloral and wild flower honey pollen spectra in Brazil. Ciência e Cultura, 48, 163-165. 74 BARTH, O . M. 1994. Monofloral and Wild Flower Honey Pollen Spectra in Brazil. Ciência e Cultura, 48, 163-165. BARTH, O. M. & DUTRA, V. M. L. 2000. Concentração de Pólen em Amostras de Mel de Abelhas Monoflorais do Brasil. Revista da Universidade de Guarulhos – Geociências. Número especial : 173-176. BASTOS, D.H.M. Análise de méis produzidos na Região Bragantina. 1994, LECTAUSF. Bra.Pta.12:121-134. BERGMAN, A. YANAI, J.; WEISS, I.; BELL, D.; MENACHEM, P.D. 1983. Acceleration of wound healing by topical application of honey. An animal model. The American Journal of Surgery, 145 : 374-376. BOGDANOV, S. 1984. Characterisation of antibacterial substaces in honey. Lebensm. Wiss. Technol., 17, 74-76. BONAGA, G. & GIUMANINI, A.G. 1986. The volatile fraction of chestnut honey. Journal Apicultural Research, 25, 113-120. BOSI,G. & BATTAGLINI,A.G.1978. Gas Chromatography analysis of free and protein amino acids in some unifloral honeys. Journal Apicultural Research, 17, 152- 166. BROMENSHENK, J.J.; et al. 1985. Pollution Monitoring of Puget Sound with honeybees. Science, NY, 227 : 632-634. BURLANDO, F. 1978. About the therapeutic action of honey on burn wounds. Minerva Dermatolog. 113: 699-706. CADAHIA, E.; CONDE, E. GARCIA-VALLEJO, M. C.; FERNÁNDEZ DE SIMÓN, B.1997. High pressure liquid chromatographic analysis of polyphenols in leaves of Eucalyptus camaldulensis, E. globulus and E. rudis.: proanthocyanidins, ellagitannins and flavonol glycosides. Phytochem. Anal., 8, 78-83. CALDEIRA, J. John's beekeeping notebook - American beekeeping history: the bee hive. Disponível em http://outdoorplace.org/beekeeping/history1.htm . Acesso em: 11/09/2002. CAMPOS, R. G. M. 1987. Contribuição para o estudo do mel, pólen, geléia real e própolis. Boletim da Faculdade de Farmacia de Coimbra, v.11,n.2, p.17-47. CARTLAND, B. 1970. The magic of honey. Corgi Books, London, UK, 160 pp. CASTRO, R. N.; AZEREDO, L. C.; AZEREDO, M.A. A. e SAMPAIO, C.S.T.2001. HPLC assay for the determination of Ascorbic Acid in honey samples. Jounal of LiquidChromatography & Related Technologies, 7(24), 1015-1020. 75 CHAPUIS-LARDY, L.; CONTOUR-ANSEL, D. & BERNHARD-RECERSAT. 2002, High-performance liquid chromatography of water-soluble phenolics in leaf litter of three Eucalyptus hybrids (Congo). Plant Science, 163, 217-222. CODEX ALIMENTARIUS COMMISSION. 1989. Codex standards for sugards (honey). Supplement 2 to Codex Alimentarius Volume III. Food and Agriculture Organization of the United Nations and World Health Organization, Rome. CODEX ALIMENTARIUS. 1994. Honey. 2nd Edition, FAO/WHO, v.11: 21-24. CODEX ALIMENTARIUS COMMISSION.1990. Official methods of analysis. v.3, Supl 2. CODEX ALIMENTARIUS. 1995. Standards for honey. 2nd Edition, FAO/WHO v.13. COHN, M.E. et al.1986. La qualite' des miels du commerce. Cah. Nut. Diet, 21 (3): 219-222. CORDELLA, C. B.; MILITÃO, J. S. L. T.; CLÉMENT, M.C.; e CABROL-BASS, D. 2003. Honey Characterization and adulteration Detection by Pattern Recognition Applied on HPAEC-PAD Profiles. 1. Honey Floral Species Characterization. J. Agric. Food Chem.; 51, 3234-3242. CORTOPASSI-LAURINO, M. & GELLY, D. S. 1991. Analyse pollinique, propriétés physico-chimiques et action antibactérienne des mieis d`abellies africanisées Apis mellifera et de Méliponinés du Brésil. Apidology, 22, 61-73. CORTOPASSI-LAURINO, M.; RAMALHO, M.1988. Pollen harvest by africanized Apis mellifeca and Trigona spinipes in São Paulo. Botanical and Ecological Views. Apidologie, 19(1): 1-24. CRANE, E. 1975. Honey: A comprehensive survey. Heinemann (in coop. with IBRA), London, U.K. 608 pp. CRANE, E. 1979. Honey in relation to infant botulism. Bee World, 60(4): 152-154. CRANE, E. 1980. A book of honey. Oxford University Press, Oxford, U.K., 198 p. CRANE, E. 1985. O livro do mel. 2ed. São Paulo: Nobel, 226p. CRANE, E. 1990. In: Bees and beekeeping: Science, Practice and World Resources. Heinemann, Oxford, 400p, Chapter 13. DAHARU, P.A. & SPORNS, P. 1984. Phenol residue levels in honey. J. Apic. Res., 23 (2): 110-113. 76 D’ARCY, B. RINTOUL,G.; ROWLAND, C.Y. E BLACKMAN, A.J.1997. Composition of Australian honey extractives. 1. Nor-isoprenoids, monoterpenes, and other natural volatiles from Blue Gum ( Eucalyptus leucoxylon) and Yellow Box ( Eucalyptus melliodora) honeys. J. Agric. Food Chem., 45, 1834-1843. DATTA, N ; TOMÁS-BARBERÁN, F.A; MARTOS, I.; FERRERES, F.; YAO, L.. & SINGANUSONG, R. 2003. Flavonoids, Phenolic acids and Abscisic acid in Australian and New Zealand Leptospermum honeys. Food Chemistry. 81,159-168. DE LIMA, NELSON MELLO. Abelhas e Mel, criação e extração . Curso de apicultura. Ed. Tecnoprint S.A 1979. DE MARIA, C. A.B.; TRUGO, L. C.; COSTA, L. S. M.; ALBUQUERQUE, M. L. S.; QUINTEIRO, L.M.C. & BARTH, O. M. 1999. Determination of non-volatile compounds of different botanical origin Brazilian honeys. Food Chemistry, 65, 347- 352. DONADIEU, Y. 1983. Honey in natural therapeutics.Paris:Maloine Editeur, S.A., 28, 2nd. DUSTMAN, J. H. 1979. Antibacterial effect of honey. Apiacta, 14(1), 7-11. EFEM, S. E. E. & UDOH, K. T. & IWARA, C. I.1992. The antimicrobial spectrum of honey and its clinical significance. Infection, 20(4), 227-229. EFEM, S.E.E. 1988. Clinical observations on the wound healing properties of honey. British Journal of Surgery, 75: 679-681. EISCHEN, F.A. & DIETZ, A. 1990. Improved culture techniques for mass rearing Galleria mellonella (Lepidoptera: Pyralidae). Entomological News, 101(2): 123-128. FERRERES, F.; ORTIZ, A.; SILVA, C.; GARCIA-VIGUERA, C.; TOMÁSBARBERÁN, F. A., & TOMÁS-LORENTE, F. 1992. Flavonoids of “ La Alcarria” honey – a study of their botanical origin. Zeitschrift-fuer Lebensmittel Untersuchung und Forschung, 194, 139-143. FERRERES, F.; GARCIA-VIGUERA, C.; TOMÁS-BARBERÁN, F. A., & TOMÁSLORENTE, F.1993. Hesperetin: amarker of the floral origin of citrus honey. Journal Scie. Food Agric., 61, 121-123. FERRERES, F.; TOMÁS-BARBERÁN, F. A.; & GINER, J. M. ; 1994. A comparative study of hesperetin and methyl anthranilate as markers of the floral origin of cutrus honey. Journal Scie. Food Agric., 65,371-372. FERRERES, F.; BLAZQUEZ, M.A.; GIL, M. I. & TOMÁS-BARBERÁN, F.A. 1994a.Separation of honey flavonoids by micellar eletrokinetic capillary chromatography. Journal Chromatography A, 669(1/2), 268-274. 77 FERRERES, F.; ANDRADE, P. & TOMÁS-BARBERÁN, F.A. 1996. Natural occurrence of abscisic acid in heather honey and floral nectar. Journal Agric. Food Chem., 44(8), 2053-2056. FERRERES, F.; JUAN, T.; PEREZ-ARQUILLUE, C.; HERRERA-MARTEACHE, A.; GARCIA-VIGUERA, C. & TOMÁS-BARBERÁN, F.A. 1998. Evaluation of pollen as a source of kaempferol in rosemary honey. Journal Scie. Food Agric., 77, 506- 510. HAFFEJEE, I.E. & MOOSA, A. 1985. Honey in the treatment of infantile gastroenteritis. Brit. Med. J. 290:1866-1867. HUIDOBRO, J. F.; SUÁREZ-LUQUE, S.; MATO,I.; SIMAL-LOZANO,J. e SANCHO, M.T. 2002. Rapid determination of minority organic acids in honey by high-performance liquid chromatography. Journal Chromatography A, 955, 207- 214. ITC, UNCTAD/GATT. 1977. Major markets for honey: Openings for quality supplies from developing countries. ITC Publications, Geneva, Switzerland, 120 pp. KANDIL, A., EL-BANBY, M.; ABDEL-WAHED, K.; ABOU SEHLY, G.; EZZAT, N. 1987. Healing effect of true floral and false nonfloral honey on medical wounds. J. of Drug Research (Egypt), 17 (1-2): 71-75. KARCH et al. 1976. Optimization of reverse-phases separation. J. Chromatography, 61: 375-377. KERKVLIET, J.D. 1981. Analysis of a toxic rhododendron honey. J. Apic. Res. 20(4): 249-253. LÜCKE, H. 1935. Wundbehandlung mit Honig und Lebertran. (Wound treatment with honey and codliver oil.) Dtsch. Mediz. Wochenschrift, 41:14-17. MARCHINI, L.C. 2001. Caracterização de amostras de méis de Apis mellifera . (Hymenoptera-apidae) do Estado de São Paulo, baseada em aspectos físicoquímicos e biológicos. Livre Docência, Piracicaba-SP, Escola Superior de Agricultura "Luiz de Queiroz", Universidade de São Paulo. MARQUEZ - SOUZA, A.C.; ABSY, M.L.; CONDÉ, P.A.A. & COELHO, H.A. 1993. Dados da obtenção do pólen por operárias de Apis mellifeca no município de JiParaná (RO), Brasil. Acta Amazonica, , 23(1):59-76. MARTOS, I.; COSSENTINI, M.; FERRERES, F.; & TOMÁS-BARBERÁN, F. A . 1997. Flavonoid composition of Tunisian honeys and propolis. Journal Agric. Food Chem. 45(8), 2824-2829. 78 MARTOS, I.; FERRERES, F.; & TOMÁS-BARBERÁN, F. A . 2000. Identification of flavonoids markers for the botanical origin of Eucaliptus honey. Journal Agric. Food Chem. 48, 1498-1502. MARTOS, I.; FERRERES, F.; YAO, L. H. ; D’ARCY, B. R.; CAFFIN, N. & TOMÁSBARBERÁN, F. A . 2000a. Flavonoids in monospecific Eucalyptus honeys from Australia. Journal Agric. Food Chem. 48, 4744-4748. MAXWELL, H. 1987. A small-scale honey drying system. Amer. Bee J., 127 (4): 284-286 Melampy, R.M. and Jones, D.B. (1939) Chemical composition and vitamin of royal jelly. Proc. Soc. Expt. Biol. Med. 41: 382-388. MENDES, B. A. & COELHO, E. M. 1983.Considerações sobre características de mel de abelhas – Análises e critérios de inspeção. Informe Agropecúario, 9(106), 56- 67. MERKEN, H. M. & GARY, R. B. 2000. Measurement of Food Flavonoids by HighPerformance Liquid Chromatography : a Review. Journal Agric. Food Chem. 48(3), 577- 599. MIORIN, P. L.; LEVY JUNIOR, N. C.; CUSTODIO, A. R.; BRETZ, W. A. & MARCUCCI, M. C.2003. Antibacterial activity of honey and propolis from Apis mellifera and Tetragonisca angustula against Stasphylococcus aureus . Journal of Applied Microbiology. 95, 913-920. MOLAN, P.C.; SMITH, I.M.; REID, G.M. 1988. A comparison of the antibacterial activity of some New Zealand honeys. J. Apic. Res., 27 (4): 252-256. MOLAN, P. C. & RUSSELL, K. M.1988. Non-peroxide antibacterial activity in some New Zealand honeys. Journal of Apicultural Research, 27(1), 62-67. MOLAN, P. C. 1992. The antibacterial activity of honey. The nature of the antibacterial activity. Bee World, 73(1), 5-28. NAGY, E., PA'PAY, V., LITKEI, G. AND DINYA, Z. 1985. Investigation of the chemical constituents, particularly the flavonoid components, of propolis and populi gemma by the GC/MS method. Studies in Organic Chemistry - Flavonoids and Bioflavonoids. 23: 223-232. NAHMIAS, F. 1981. Cure yourself with honey. Curatevi con il miele. De Vecchi Editore, Milano, 125 pp. NOGUEIRA NETO, P. 1972. Notas sobre a história da apicultura no Brasil. In: Camargo, J.M.F. Manual de apicultura. São Paulo: CERES. 17-32. PAVIA, D. & LAMPMAN, K. G. 1979. Ultraviolet spectroscopy. In: Introduction to spectroscopy – a guide for students of organic Chemistry. Sauders College Publishing/Holt Rinehart and Winston. p.183-224. 79 PERSANO ODDO, L. & RICCIARDELLI D`ALBORE, G. 1989. Nomenclatura melissopalinológica. Apicultura. 5, 63-72. PLATT, J.L. & ELLIS, J.R.B. 1985. Removing water from honey at ambient pressure. US Patent, 4,536,973: 6 pp. RAMALHO, M.; GUIBU, L.S.; GIANINI, T.C.; KLIEINER-GIOVANINI, A.; IMPERATRIZ-FONSECA, V.L. 1991.Characterization of some southern Brazilian honey and bee plants through pollen analysis. J.Apic. Research., 30(2): 81-86. RICCIARDELLI D'ALBORE, G. 1978. L'Apicoltura nello Stato di S.Catarina (Brasile): caratteristiche microscopiche e fisico-chimiche dei mieli che vi si producono. Rivista de Agricultura Subtropicale e tropicale, 271-289. RODRIGUEZ LOPEZ, C. 1985. Determinacion espectro-fotométrica del color de las mieles. Vida Apic., 16: 24-29. SABATIER, S. AMIOT, M.J. TACCHINI, M. & AUBERT, S. 1992. Identification of flavonoids in sunflower honey. Journal Food Science, 57(3), 733-734 SAKAKIBARA,H.; HONDA, Y.; NAKAGAWA, H. A. & KANAZAWA.2003. Simultaneous Determination od all Polyphenols in Vegetables, Fruits and Teas. J.Agric. Food Chem.51, 571-581. SANTOS, C.F.O. 1961.Principais Tipos de Pólen Encontrados em algumas Amostras de mel. Revista de Agricultura, 36; 93-96. SANTOS, A.1974. Análise polínica de Alguns Méis do Estado de São Paulo. Anais do III Congresso Brasileiro de Apicultura, Piracicaba, São Paulo. SATO, T. & MIYATA, G. 2000. The nutraceutical benefit, Part III: Honey. Nutrition 16:468-469. SERRANO, R. B.; VILLANUEVA, M. T. O.; MARQUINA, A. D. 1994. La miel. Edulcorante natural por excelência. Alimentaria. 253, 25-35. SILVEIRA, F.A. 1996. A importância da palinologia nos estudos apícolas. Anais do XI Congresso Brasileiro de Apicultura, Teresina, Piauí. 269-273. SILVIO, L.2003. A história do mel. http://www.cpamn.embrapa.br/pesquisa. Acesso em 02/09/2003. SHAMBAUGH, P.; WORTHINGTON, V.; HERBERT, J.H. 1990. Differential effects of honey, sucrose, and fructose on blood sugar levels. J. Manipul. Physiol. Therapeutics, 13 (6): 322-325 80 SOLER, C.; GIL, M.I.; GARCIA-VIGUERA, C. e TOMÁS-BARBERÁN, F.A. 1995. Flavonoids patterns of French honeys with different floral origen. Apidologie,26, 53-60. STEEG, E. & MONTAG, A. 1988. Qiantitative determination of aromatic carboxylic acids in honey. Zeitschrift fuer Lebensmittel Untersuchung und Forschung, 187, 115-120. STONOGA, V.I., FREITAS, R.J.S.D.1991. Conteúdo de água e açúcares em mel de abelhas. Bd. Ceppa, Curitiba; 9 (1), 9-16. STRINSON, E.E., SUBES, M.H., PETTY, J., WHITE, J.W., JR. 1960.The composition of honey. V. Separation and identification of the organic acids. Arch. Biochemestry Biophys, 89, 6-12. SUBRAHMANYAM, V.M. 1993. Storage of skin grafts in honey. Bee Well 3(1): 6. TAN, S. T., HOLLAND, P. T., WILKINS, A. L., & MOLAN, P. C. 1988. Extractives from New Zealand Honeys. 1. White clover, manuka and kanuka unifloral honeys. Journal of Agricultural and Food Chemistry, 36, 453-460. TAN, S.T.; WILKINS, A.L.; MOLAN, P.C.; HOLLAND, P.T. e REID, M. 1989. A Chemical approach to the determination of floral sources of new Zealand honeys. Journal of Apicultural Research,28, 212-222. THE VIRTUAL BEEKEEPING GALLERY. Bee Products. http://www.apiculture.com/_menus_us/index.htm?menu.htm&0. Acesso em: 06/06/. 2003. TERRAB, A.; DFEZ, M. J. & HEREDIA, F.J. 2003. Palynological, Physico-chemical and colour characterization of Moroccan honeys: I. River red gum (Eucalyptus camaldulensis Dehnh) honey. International Journal of Food Science and Technology. 38, 379-386. TOMÁS-BARBERÁN, F.A; FERRERES, F. & BLÁZQUEZ, M. A. ; 1993a. Highperformance liquid chromatography of honey flavonoids. Journal of Chromatography, 634, 41-46. TOMÁS-BARBERÁN, F.A; FERRERES, F.; GARCIA-VIGUERA, C.; & TOMÁSLORENTE, F. 1993. Flavonoids in honey of different geographical origin. Zeitschrift-fuer Lebensmittel Untersuchung und Forschung. 196, 38-44. TOMÁS-BARBERÁN, F.A; FERRERES, F. & GINER, J. M. 1994. A comparative study of hesperetin and methyl anthranilate as markers of the floral origin of citrus honey. J. Sci. Agric. 65, 371-372 TOMÁS-BARBERÁN, F.A; FERRERES, F. e TOMÁS-LORENTE , F. e GARCÍAVIGUERA, C. 1993b.Hesperetin: A marker of the floral origin of citrus honey. J. Sci. Food Agric.; 61, 121-123. TOMÁS-BARBERÁN, F.A; MARTOS, I.; FERRERES, F.; RADOVIC, B. S. e ANKLAM,E. 2001. HPLC flavonoid profiles as markers for the botanical origin of European unifloral honeys. J. Sci.Food Agric., 81, 485-496. TONG, S.S. C.; et al. 1975. Elemental analysis of honey as an indicator of pollution:forty-seven elements in honeys produced near highway, industrial and mining areas. Archs Envir. Hith, 30 (7): 329-332. TOTH, G.; LEMBERKOVICS, E. A; KUTASI-SZABO, J. 1987. The volatile components of some Hungarian honeys and their antimicrobial effects. Amer. Bee J., 127 (7): 496-497. VERISSIMO, M.T.L.1987. Porque o mel cristaliza. Apicultura no Brasil, 3(18),14. WAHDAN, H.A.L. 1998. Causes of the Antimicrobial Activity of Honey. Infection, 26 (1), 26-31. WESTON, R. J.; MITCHELL, K. R.; e ALEEN, K. L. 1999. Antibacterial phenolioc components of New Zealand manuka honey. Food Chemistry. 64, 295-301. WESTON, R. J.; BROCKLEBANK, L. K. e LU, Y. 2000. Identification and quantitative levels of antibacterial components of some New Zealand honeys. Food Chemistry; 70, 427-435. WHITE, J. W. & SUBERS, M.H. 1963. Studies on honey inhibine. 3. Effect of heat. Journal of Apicultural Research, 2(2),93-100. WHITE, J. W. & SUBERS, M.H. & SHEPARTZ, A.I. 1966. The identification of inhibine, the antibacterial factor in honey, as hudrogen peroxide and its origin in a honey glucose oxidase system. Biochimica et Biophysica Acta, 73, 57-70. WHITE, J. W. & KUSHINIR, I. 1967. The enzimes of honey: examination by ionexchange chromatography, gel filtration, and starch-gel electrophoresis. Journal of Apicultural Research, 6(2); 69-89. WHITE, J.W. 1975. Physical characteristics of honey. In: CRANE, E. Honey a comprehensive survey. London: Heinemann,Cap.6, p.207-239. WHITE, J.W. 1975c. Honey. In: The hive and the honeybee. Dadant & Sons Inc., Hamilton Illinois, USA, 491-530. WHITE, J.W. & DONER, L.W. 1978. The C13/C12 ratio in honey. J. Apic. Res., 17, 94-99. 82 WHITE, J.W. & RUDYJ, O.N. 1978. The protein conten in honey. Journal of Apicultural Research, 1784, 234-38. WHITE, J.W. JR.; KUSHNIR, I.; DONER, L.W. 1979. Charcoal column/thin layer chromatographic method for high fructose corn syrup in honey and spectrophotometric method for hydroxymethylfurfural in honey: collaborative study. J. Assn. Off. Anal. Chem. 62(4): 921-927. WHITE, J.W. & SICILIANO, J. 1980. Hydroxymethylfurfural and honey adulteration. J. Ass. Off. Analyt. Chem., 63 (1): 7-10. WHITE, J.W. 1980. Hydroxymethylfurfural content of honey as an indicator of its adulteration with invert sugars. Bee World, 61(1): 29-37. WOOTON, M., EDWARDS, R.A. & FARAJI-HAREMI, R. 1976. Effect of accelerated storage conditions on the chemical compostion and properties of australian honeys. 2. Changes in sugar and free amino acid contents. Journal of Apicultural Research; 15(1), 29-34. WOOTON, M. et al.1985. A comparison of Codex Alimentarius Commission and HPLC methods for 5-hydroxymethyl-2-furaldehyde determination in honey. Journal of Apicultural Research, 24(2), 120-124. ZWAENEPREL, C. 1984. Honey: facts and folklore. Alberta Beekeepers' Association, Edmonton, Canada, 24 p.por
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